ORIGIN OF THE POSITIVE EFFECT OF COKE DEPOSITS ON THE SKELETAL ISOMERIZATION OF N-BUTENES OVER A H-FER ZEOLITE

被引：74

作者：

GUISNET, M ^{[1
]}

ANDY, P ^{[1
]}

GNEP, NS ^{[1
]}

TRAVERS, C ^{[1
]}

BENAZZI, E ^{[1
]}

机构：

[1] INST FRANCAIS PETR,F-92506 RUEIL MALMAISON,FRANCE

来源：

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS | 1995年 / 16期

关键词：

D O I：

10.1039/c39950001685

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The curious positive effect of carbonaceous deposits on the skeletal isomerization of n-butenes over a H-FER zeolite can be related to the development of a new reaction mechanism involving as active sites tertiary carbenium ions blocked in the zeolite pores.

引用

页码：1685 / 1686

页数：2