CHEMILUMINESCENT REACTION (BA+CL-2) WITHIN LARGE ARGON CLUSTERS

被引：12

作者：

BIQUARD, X ^{[1
]}

SUBLEMONTIER, O ^{[1
]}

BERLANDE, J ^{[1
]}

GAVEAU, MA ^{[1
]}

MESTDAGH, JM ^{[1
]}

SCHILLING, B ^{[1
]}

VISTICOT, JP ^{[1
]}

机构：

[1] CE SACLAY, CEA, DSM, DRECAM, SPAM, F-91191 GIF SUR YVETTE, FRANCE

来源：

JOURNAL DE CHIMIE PHYSIQUE ET DE PHYSICO-CHIMIE BIOLOGIQUE | 1995年 / 92卷 / 02期

关键词：

D O I：

10.1051/jcp/1995920264

中图分类号：

Q5 [生物化学]; Q7 [分子生物学];

学科分类号：

071010 ; 081704 ;

摘要：

Chemiluminescence produced by the reactive collision of barium and chlorine molecule on an 8000 argon cluster is investigated. The binary collision Ba + Cl-2 on the cluster leads to the observation of the reaction intermediate BaCl2 as the dominant luminescent product whereas in the gas phase, under the single collision regime, the reaction leads exclusively to the formation of the radical pair BaCl* + Cl. This result is interpreted as a very efficient trapping of the BaCl2 intermediate by the cluster. Trapping mechanisms are discussed.

引用

页码：264 / 282

页数：19

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