HYDROFORMYLATION OF HOMOLOGOUS OMEGA-ALKENECARBOXYLATES WITH WATER-SOLUBLE RHODIUM CARBONYL/TERT PHOSPHANE COMPLEX CATALYST SYSTEMS

被引：35

作者：

FELL, B

SCHOBBEN, C

PAPADOGIANAKIS, G

机构：

[1] Institut für Technische Chemie, Petrolchemie der Rheinisch-Westfälischen Technischen Hochschule Aachen, D-52056 Aachen

来源：

JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL | 1995年 / 101卷 / 03期

关键词：

HYDROFORMYLATION; MICELLAR CATALYSIS; WATER SOLUBLE COMPLEXES; RHODIUM; UNSATURATED CARBOXYLIC ACID ESTERS;

D O I：

10.1016/1381-1169(95)00064-X

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Homologous omega-alkene carboxylic acid methyl esters have been hydroformylated using the water-soluble rhodiumcarbonyl/triphenylphosphine-m-trisulfonic acid sodium salt-catalyst in an aqueous-organic two-phase system. The homologous omega-alkene carboxylic acid esters possess a water solubility which allows hydroformylation reactions in the two-phase system up to omega-decene carboxylic acid methyl ester. Higher omega-alkene carboxylic acid esters which are water insoluble starting materials have been hydroformylated by addition of tensids in a micellar system. Cationic tensids are the best system for this hydroformylation. The cationic tensids have two effects. Firstly they cause the higher olefines to become soluble in aqueous media. Secondly, due to their positive charge, the concentration of the negatively charged rhodium complex ions is increased in the micelles.

引用

页码：179 / 186

页数：8

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