REACTION OF (ETA-5-C13H9)MN(CO)3 WITH ALKYLPHOSPHINES - FORMATION AND ISOLATION OF ETA-1-FLUORENYL COMPLEXES

被引：34

作者：

BIAGIONI, RN ^{[1
]}

LORKOVIC, IM ^{[1
]}

SKELTON, J ^{[1
]}

HARTUNG, JB ^{[1
]}

机构：

[1] GRINNELL COLL,DEPT CHEM,GRINNELL,IA 50112

来源：

ORGANOMETALLICS | 1990年 / 9卷 / 03期

关键词：

D O I：

10.1021/om00117a002

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Reaction of (η5-C13H9)Mn(CO)3 with L = PEt3 or PBu3 leads to formation of (η1-C13H9Mn(CO)3L2. The L = PEt3 complex was isolated analytically pure in moderate yield and characterized as the trans-meridional isomer by1H,31P, and13C NMR and IR spectroscopies. (η1-C13H9)Mn(CO)3L2 decomposes via Mn-C bond homolysis to the C13H9 radical and Mn(CO)3L2, which reacts further to yield HMn(CO)3L2. (η1-C13H9)Mn(CO)3L2 can also be prepared by reacting L with (η6-C13H9)Mn(CO)3, apparently via a novel η6 to η1 shift. © 1990, American Chemical Society. All rights reserved.

引用

页码：547 / 551

页数：5

共 19 条

[1] HAPTOTROPIC REARRANGEMENTS OF POLYENE-MLN COMPLEXES .2. BICYCLIC POLYENE-MCP, POLYENE-M(CO)3 SYSTEMS
ALBRIGHT, TA
HOFMANN, P
HOFFMANN, R
LILLYA, CP
DOBOSH, PA
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1983, 105 (11) : 3396 - 3411
[2] METAL FORMYL AND HYDROXYMETHYL METAL-COMPOUNDS
CASEY, CP
ANDREWS, MA
MCALISTER, DR
JONES, WD
HARSY, SG
[J]. JOURNAL OF MOLECULAR CATALYSIS, 1981, 13 (01): : 43 - 59
[3] ETA-5 TO ETA-1 CONVERSIONS OF INDENYLTRICARBONYLRHENIUM
CASEY, CP
OCONNOR, JM
[J]. ORGANOMETALLICS, 1985, 4 (02) : 384 - 388
[4] INTERMEDIATES IN ASSOCIATIVE PHOSPHINE SUBSTITUTION-REACTIONS OF (N5-C5H5)W(CO)2(NO)
CASEY, CP
JONES, WD
HARSY, SG
[J]. JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1981, 206 (03) : C38 - C42
[5] CONVERSION OF AN ETA-5-CYCLOPENTADIENYL-METAL COMPLEX TO AN ETA-1-CYCLOPENTADIENYL-METAL COMPLEX UPON ADDITION OF TRIMETHYLPHOSPHINE
CASEY, CP
JONES, WD
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1980, 102 (19) : 6154 - 6156
[6] INTERMEDIATES IN THE ASSOCIATIVE PHOSPHINE SUBSTITUTION-REACTION OF (ETA-5-C5H5)RE(CO)3
CASEY, CP
OCONNOR, JM
JONES, WD
HALLER, KJ
[J]. ORGANOMETALLICS, 1983, 2 (04) : 535 - 538
[7] INTERCONVERSION OF ETA-5-C5H5, ETA-1-C5H5, AND IONIC ETA-0-C5H5 RHENIUM COMPOUNDS - X-RAY CRYSTAL-STRUCTURE OF [RE(NO)(CH3)(PME3)4]+[C5H5]-
CASEY, CP
OCONNOR, JM
HALLER, KJ
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1985, 107 (05) : 1241 - 1246
[8] REDUCTION-OXIDATION PROPERTIES OF ORGANOTRANSITION-METAL COMPLEXES .5. ONE-ELECTRON OXIDATION OF TRICARBONYL(ETA-CYCLOPENTADIENYL)-MANGANESE DERIVATIVES AND REACTIVITY OF RESULTING RADICAL CATIONS
CONNELLY, NG
KITCHEN, MD
[J]. JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1977, (09): : 931 - 937
[9] THERMAL SYNTHESIS AND STRUCTURAL CHARACTERIZATION OF RE(CO)3(PCY3)2, A RHENIUM(O) RADICAL
CROCKER, LS
HEINEKEY, DM
SCHULTE, GK
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1989, 111 (01) : 405 - 406
[10] JAMESON CJ, 1987, PHOSPHOROUS 31 NMR S, V8, pCH6

← 1 2 →