THE GENERATION AND REACTIVITY OF OXYGEN CENTERED RADICALS FROM THE PHOTOLYSIS OF DERIVATIVES OF N-HYDROXY-2-THIOPYRIDONE

被引：66

作者：

BARTON, DHR

JASZBERENYI, JC

MORRELL, AI

机构：

[1] Department of Chemistry, Texas A and M University, College Station

来源：

TETRAHEDRON LETTERS | 1991年 / 32卷 / 03期

基金：

美国国家卫生研究院;

关键词：

D O I：

10.1016/S0040-4039(00)92615-7

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Oxygen centered radicals, formed by the photolysis of derivatives of N-hydroxy-2-thiopyridone, have been trapped by vinyl ethers. In the case of the benzoyloxy radical, smooth deoxygenation is effected by (III)P compounds. Evidence for the formation of the dimethyl(t)butylsilyloxy and of the hydroxy radical is also presented.

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页码：311 / 314

页数：4

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