SONOCHEMICAL REDUCTION OF ALPHA,BETA-EPOXY KETONES AND ALPHA'-OXYGENATED ANALOGS BY ALUMINUM AMALGAM

被引：26

作者：

MORENO, MJSM

MELO, MLSE

NEVES, ASC

机构：

[1] Lab. de Química Farmacêutica, Faculdade de Farmácia, Universidade de Coimbra

来源：

TETRAHEDRON LETTERS | 1993年 / 34卷 / 02期

关键词：

D O I：

10.1016/S0040-4039(00)60586-5

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

The sonochemical reductive opening of alpha,beta-epoxy ketones and their alpha'-oxygenated (-OH or -OAc) analogs by aluminium amalgam allows shorter reaction times better yields of the respective beta-hydroxy ketones and minimization of by-products. The rates of these reactions are affected by the intensity ot the acoustic waves and by temperature.

引用

页码：353 / 356

页数：4

共 8 条

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