A PRONOUNCED AXIAL LIGAND EFFECT ON THE REACTIVITY OF OXOIRON(IV) PORPHYRIN CATION RADICALS

被引：139

作者：

GROSS, Z

NIMRI, S

机构：

[1] Department of Chemistry, The Technion, Israel Institute of Technology, Technion City

来源：

INORGANIC CHEMISTRY | 1994年 / 33卷 / 09期

关键词：

D O I：

10.1021/ic00087a001

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The rate constants for the epoxidation of styrene by six oxoiron(IV) porphyrin cation radicals 1-X (X = -F, HOCH3, -Cl, -OAc, -OSO2CF3, -OClO3) which differ only in the identity of their axial ligan were obtained under conditions where the presence of the axial ligands during the reactions could be ascertained. A qualitative relationship was found between the field strengths of the ligands and their pronounced effect on the reactivity of 1-X.

引用

页码：1731 / 1732

页数：2

共 17 条

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