A NOVEL SODIUM TEMPLATE APPROACH FOR PREPARING TETRAIMINE MACROCYLES OF 2,6-DIFORMYL-4-METHYLPHENOL AND DIAMINO DERIVATIVES

被引：44

作者：

GOU, SH ^{[1
]}

FENTON, DE ^{[1
]}

机构：

[1] UNIV SHEFFIELD,DEPT CHEM,SHEFFIELD S3 7HF,S YORKSHIRE,ENGLAND

来源：

INORGANICA CHIMICA ACTA | 1994年 / 223卷 / 1-2期

基金：

中国国家自然科学基金;

关键词：

ALKALI METAL COMPLEXES; MACROCYCLE COMPLEXES; IMINE COMPLEXES;

D O I：

10.1016/0020-1693(94)03994-1

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

A number of [2 + 2] tetraimine macrocycles were synthesised, employing sodium 2,6-diformyl-4-methylphenolate as a precursor to undergo Schiff base condensation with a series of diamino compounds. The resulting dinuclear sodium macrocyclic complexes have been spectroscopically characterised by IR, mass and H-1 NMR spectra. The sodium ion here plays a unique template role in the formation of macrocycles with different sizes of cavity in comparison to the other common-used templates such as alkaline earth metal, transition metal and rare earth metal ions.

引用

页码：169 / 172

页数：4

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