X-RAY-DIFFRACTION EVIDENCE FOR A CYCLOHEXATRIENE MOTIF IN THE MOLECULAR-STRUCTURE OF TRIS(BICYCLO[2.1.1]HEXENO)BENZENE - BOND ALTERNATION AFTER THE REFUTATION OF THE MILLS-NIXON THEORY

被引：124

作者：

BURGI, HB

BALDRIDGE, KK

HARDCASTLE, K

FRANK, NL

GANTZEL, P

SIEGEL, JS

ZILLER, J

机构：

[1] UNIV CALIF SAN DIEGO, DEPT CHEM, LA JOLLA, CA 92093 USA

[2] SAN DIEGO SUPERCOMP CTR, SAN DIEGO, CA USA

[3] CALIF STATE UNIV NORTHRIDGE, DEPT CHEM, NORTHRIDGE, CA 91330 USA

[4] UNIV CALIF IRVINE, DEPT CHEM, IRVINE, CA 92717 USA

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 1995年 / 34卷 / 13-14期

关键词：

BOND LENGTH ALTERNATION; CYCLOHEXATRIENE; MILLS-NIXON EFFECT;

D O I：

10.1002/anie.199514541

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Cyclohexatriene lost, cyclohexatriene regained! Recently the Mills–Nixon postulate concerning the structure of benzene derivatives was recognized to be invalid. A new view on strain‐induced bond localization in benzene led to the design and synthesis of tris(bicyclo[2.1.1]hexeno)benzene (1), which shows significant distortion toward a cyclohexatriene geometry. (Figure Presented.) Copyright © 1995 by VCH Verlagsgesellschaft mbH, Germany

引用

页码：1454 / 1456

页数：3

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