ALKYLATION OF [WS4](2-) - SYNTHESIS AND STRUCTURAL CHARACTERIZATION OF THE ETHYLTHIOLATOTRITHIOTUNGSTATE(VI) ANION

被引：35

作者：

BOORMAN, PM

WANG, MP

PARVEZ, M

机构：

来源：

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS | 1995年 / 10期

关键词：

D O I：

10.1039/c39950000999

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Reaction of [PPh(4)](2)[WS4] with ethyl bromide yields the tetraphenylphosphonium salt of the title anion 1, for which an X-ray structure determination reveals no evidence for an intramolecular redox reaction, but concentrated solutions undergo rapid reactions leading to [W3S9](2-) and Et(2)S(x)(x = 1-3).

引用

页码：999 / 1000

页数：2

共 22 条

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