CHIRAL COMPLEXES DERIVED FROM MONOCYCLOPENTADIENYLTITANIUM(IV) - DIASTEREOTOPY AND DIASTEREOISOMERISM OF THE COMPLEXES CP TIA(Z-Z) PRESENTING A BIDENTATE SIGMA LIGAND

被引：20

作者：

DORMOND, A

KOLAVUDH, T

TIROUFLET, J

机构：

[1] Laboratoire de Polarographie Organique associé au C.N.R.S. (L.A. 33), Faculté des Sciences Gabriel, 21100 Dijon, 6, Boulevard Gabriel

来源：

JOURNAL OF ORGANOMETALLIC CHEMISTRY | 1979年 / 164卷 / 03期

关键词：

D O I：

10.1016/S0022-328X(00)81695-2

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The reaction 1 has been used to obtain monocyclopentadienyltitanium(IV) {A figure is presented} (HZZ′H = disymmetric diphenol or dithiol; R• = Cl• or SR• from CCl4 or RSSR) chiral complexes with three σ bonds. The chirality at the titanium atom is detected either by NMR analysis (diastereotopy of methyl groups when Cp′ = η5-C5H4CHMe2) and by characterization of diastereoisomer pairs (Cp′ = η5-C5H4 C *CHMeC6H5). © 1979.

引用

页码：317 / 327

页数：11

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[No title captured]

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