TEMPLATE SYNTHESIS OF A FERROCENE METALLOCYCLAM CONJUGATE

被引：5

作者：

DEBLAS, A

DESANTIS, G

FABBRIZZI, L ^{[1
]}

LICCHELLI, M

MANGANO, C

PALLAVICINI, P

机构：

[1] UNIV PAVIA,DIPARTIMENTO CHIM GEN,TARAMELLI 12,I-27100 PAVIA,ITALY

[2] UNIV VIGO,DEPT QUIM PURA & APLICADA,VIGO,SPAIN

来源：

INORGANICA CHIMICA ACTA | 1992年 / 202卷 / 01期

关键词：

D O I：

10.1016/S0020-1693(00)85360-8

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Arylsulfonamides act as efficient locking fragments in the Ni(II) template cyclization of open-chain tetramines, in the presence of formaldehyde, to give cyclam-like azamacrocycles. In particular, if ferrocenesulfonamide is used, a ferrocene-metallocyclam conjugate is obtained, which releases two electrons according to two distinct and consecutive one-electron steps (Fc/Fc+ and Ni(II)/Ni(III)).

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页码：115 / 118

页数：4

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