PREPARATION AND CHARACTERIZATION OF TITANOSILICATES WITH ZSM-5 STRUCTURE

被引：27

作者：

SULIKOWSKI, B ^{[1
]}

KLINOWSKI, J ^{[1
]}

机构：

[1] UNIV CAMBRIDGE, DEPT CHEM, LENSFIELD RD, CAMBRIDGE CB2 1EW, ENGLAND

来源：

APPLIED CATALYSIS A-GENERAL | 1992年 / 84卷 / 02期

关键词：

CATALYST CHARACTERIZATION (FT-IR; NMR; SEM; TEM; XRD); CATALYST PREPARATION (RUTILE); CYCLOHEXANOL OXIDATION; CYCLOHEXANONE; RUTILE; TITANOSILICATES; ZEOLITES;

D O I：

10.1016/0926-860X(92)80112-P

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

A titanosilicate with the crystal structure of zeolite ZSM-5 was prepared via the non-alkaline "fluoride" route using rutile as the source of titanium. The properties of the product are compared with those of silicalite, the purely siliceous analogue of ZSM-5, and a sample prepared by a post-synthesis treatment of silicalite with TiCl4. Zeolites [Si,Ti]-ZSM-5 selectively catalyse the liquid-phase oxidation of cyclohexanol to cyclohexanone.

引用

页码：141 / 153

页数：13

共 25 条

[1] SYNTHESIS AND CHARACTERIZATION OF DEFECT-FREE CRYSTALS OF MFI-TYPE ZEOLITES [J].

AXON, SA ;

KLINOWSKI, J .

APPLIED CATALYSIS A-GENERAL, 1992, 81 (01) :27-34

[2] THE DETERMINATION OF PORE VOLUME AND AREA DISTRIBUTIONS IN POROUS SUBSTANCES .1. COMPUTATIONS FROM NITROGEN ISOTHERMS [J].

BARRETT, EP ;

JOYNER, LG ;

HALENDA, PP .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1951, 73 (01) :373-380

[3]

CARROTT PJM, 1986, CHEM IND-LONDON, P786

[4]

ENGELHARDT G, 1984, STUD SURF SCI CATAL, V18, P23

[5]

ENGELHARDT G, 1989, RECENT ADV ZEOLITE S, V52, P151

[6]

Guth J., 1986, STUD SURF SCI CAT, V28, P121

[7]

HOCEVAR S, 1982, J CATAL, V73, P205

[8] ZEOLITES - CATALYSTS FOR ORGANIC SYNTHESES [J].

HOLDERICH, W ;

HESSE, M ;

NAUMANN, F .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH, 1988, 27 (02) :226-246

[9] PROPERTIES OF THE END MEMBERS IN THE PENTASIL-FAMILY OF ZEOLITES - CHARACTERIZATION AS ADSORBENTS [J].

JACOBS, PA ;

BEYER, HK ;

VALYON, J .

ZEOLITES, 1981, 1 (03) :161-168

[10]

JACOBS PA, 1987, STUDIES SURFACE SCI, V33, P26

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