REACTIONS OF COBALT COMPOUNDS WITH NITROSO-NAPTHOLS .2. MECHANISM OF REACTION BETWEEN COBALTOUS IONS AND 1-NITROSO-2-NAPTHOL-3,6-DISULPHONIC ACID

被引：23

作者：

LALOR, GC

机构：

[1] Chemistry Department, University of the West Indies, Mona

来源：

JOURNAL OF INORGANIC & NUCLEAR CHEMISTRY | 1969年 / 31卷 / 06期

关键词：

D O I：

10.1016/0022-1902(69)80396-9

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Stoicheiometric and kinetic studies are reported for the reaction between cobaltous ions and the potassium salt of 1-nitroso-2-napthol-3,6-disulphonic acid. The product of the reaction is the tris-(1-nitroso-2-napthol-3,6-disulphonate) cobalt(III) complex. In alkaline solution oxidation to cobalt(III) is brought about by oxygen. In acidic solution the uncomplexed ligand itself is the oxidant. © 1969.

引用

页码：1783 / &

共 4 条

[1] THE COMPOSITION AND FORMATION OF COBALT COMPLEXES WITH 1-NITROSO-2-NAPHTHOL
KOLTHOFF, IM
JACOBSEN, E
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1957, 79 (14) : 3677 - 3681
[2] REACTIONS OF COBALTAMMINES WITH 1-NITROSO-2-NAPHTHOL-3,6-DISULPHONIC ACID
LALOR, GC
[J]. JOURNAL OF INORGANIC & NUCLEAR CHEMISTRY, 1968, 30 (07): : 1925 - &
[3] MORGAN GT, 1921, J CHEM SOC, P704
[4] Yoe JH, 1944, INDIAN ENG CHEM ANAL, V16, P111, DOI [10.1021/i560126a015, DOI 10.1021/I560126A015]

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