SOLITON - ASSISTED ACTIVATION PROCESSES

被引:11
作者
EBELING, W
JENSSEN, M
机构
来源
BERICHTE DER BUNSEN-GESELLSCHAFT-PHYSICAL CHEMISTRY CHEMICAL PHYSICS | 1991年 / 95卷 / 03期
关键词
ACTIVATION; CHEMICAL KINETICS; NONEQUILIBRIUM PHENOMENA; NONLINEAR PHENOMENA; SOLUTIONS;
D O I
10.1002/bbpc.19910950323
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
This paper deals with the problem of energetic activation of one or few degrees of freedom of a spatially extended system. The fusion of soliton-like excitations is an efficient nonlinear mechanism to generate high-energy events at soft springs which are embedded in a one-dimensional chain of hard springs. In equilibrium there exists an optimum temperature where thermal energy is mainly partitioned to the soft springs due to the superposition of thermally generated solitons. Some of the features obtained for the one-dimensional system also apply to a solution of soft spheres in a hard-sphere solvent.
引用
收藏
页码:356 / 362
页数:7
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