REACTION OF TRICHLOROMETHYL AND TRICHLOROMETHYLPEROXYL RADICALS WITH C-60 - A PULSE-RADIOLYSIS STUDY

被引:41
作者
DIMITRIJEVIC, NM
机构
[1] Radiation Laboratory, University of Notre Dame, Notre Dame
关键词
D O I
10.1016/0009-2614(92)86082-S
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
Both trichloromethyl (.CCl3) and trichloromethylperoxyl (CCl3OO.) radicals react with C60. The bimolecular rate constants are (2.7+/-0.5)x10(8) mol-1 dm3 s-1 and 2x10(6) mol-1 dm3 s-1, respectively. The transient absorption spectra of the radical adducts are presented.
引用
收藏
页码:457 / 460
页数:4
相关论文
共 24 条
  • [1] CHARACTERIZATION OF THE SOLUBLE ALL-CARBON MOLECULES C60 AND C70
    AJIE, H
    ALVAREZ, MM
    ANZ, SJ
    BECK, RD
    DIEDERICH, F
    FOSTIROPOULOS, K
    HUFFMAN, DR
    KRATSCHMER, W
    RUBIN, Y
    SCHRIVER, KE
    SENSHARMA, D
    WHETTEN, RL
    [J]. JOURNAL OF PHYSICAL CHEMISTRY, 1990, 94 (24) : 8630 - 8633
  • [2] ALFASSI ZB, 1988, CHEM KINETICS SMALL, V3, P41
  • [3] DOSE RATE EFFECTS IN STEADY AND PULSE RADIOLYSIS OF LIQUID CHLOROFORM
    BIBLER, NE
    [J]. JOURNAL OF PHYSICAL CHEMISTRY, 1971, 75 (16) : 2436 - &
  • [4] PHOTOCHEMICAL PRIMARY REACTIONS OF ALPHA BRANCHED ALIPHATIC-KETONES AND ALDEHYDES IN SOLUTION
    BLANK, B
    HENNE, A
    FISCHER, H
    [J]. HELVETICA CHIMICA ACTA, 1974, 57 (03) : 920 - 936
  • [5] PRIMARY PROCESSES OF THE RADIATION-INDUCED CATIONIC POLYMERIZATION OF AROMATIC OLEFINS STUDIED BY PULSE-RADIOLYSIS
    BREDE, O
    BOS, J
    HELMSTREIT, W
    MEHNERT, R
    [J]. RADIATION PHYSICS AND CHEMISTRY, 1982, 19 (01): : 1 - 15
  • [6] THE CATIONS OF CC14 IN NON-POLAR LIQUID-SYSTEMS
    BUHLER, RE
    [J]. RADIATION PHYSICS AND CHEMISTRY, 1983, 21 (1-2): : 139 - 146
  • [7] DIRECT MEASUREMENT OF THE ABSOLUTE KINETICS OF CHLORINE ATOM IN CCL4
    CHATEAUNEUF, JE
    [J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1990, 112 (01) : 442 - 444
  • [8] den Hollander J. A., 1971, Chemical Physics Letters, V10, P430, DOI 10.1016/0009-2614(71)80327-5
  • [9] EMMI SS, 1989, RADIAT PHYS CHEM, V33, P29
  • [10] QUANTITATIVE CHEMICALLY-INDUCED NUCLEAR-POLARIZATION (CIDNP) STUDY OF KINETICS OF PHOTOLYSIS OF PIVALOPHENONE IN VARIOUS SOLUTIONS
    FRITH, PG
    MCLAUCHLAN, KA
    [J]. JOURNAL OF THE CHEMICAL SOCIETY-FARADAY TRANSACTIONS II, 1976, 72 : 87 - 103