AN EXTREMELY MILD 3-AZA-CLAISEN REACTION .2. NEW CONDITIONS AND THE REARRANGEMENT OF ALPHA-HETEROATOM SUBSTITUTED AMIDES

被引：22

作者：

WALTERS, MA

HOEM, AB

ARCAND, HR

HEGEMAN, AD

MCDONOUGH, CS

机构：

[1] Dartmouth College, 6128 Burke Laboratory, Department of Chemistry, Hanover

来源：

TETRAHEDRON LETTERS | 1993年 / 34卷 / 09期

关键词：

D O I：

10.1016/S0040-4039(00)60316-7

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Several new and potentially useful reaction conditions for the 3-aza-Claisen rearrangement of N-allyl amides have been developed. These new conditions have been successfully applied to the rearrangement of alpha-heteroatom substituted species forming alpha-amino nitriles and protected cyanohydrins as products.

引用

页码：1453 / 1456

页数：4

共 17 条

[1] SIMULTANEOUS ACTION OF PHOSPHINES TOGETHER WITH CARBON-TETRACHLORIDE ON AMMONIA (DERIVATIVES) .12. 2 NEW METHODS FOR PREPARATION OF IMIDOYL HALIDES [J].