SYNTHESIS AND STRUCTURE OF A NEW BIS[(TRIMETHYLPHOSPHANE)TITANOCENE] COMPLEX WITH A BRIDGING C-2 UNIT

被引：44

作者：

BINGER, P

MULLER, P

PHILIPPS, P

GABOR, B

MYNOTT, R

HERRMANN, AT

LANGHAUSER, F

KRUGER, C

机构：

来源：

CHEMISCHE BERICHTE-RECUEIL | 1992年 / 125卷 / 10期

关键词：

TITANOCENE COMPLEXES; CYCLOPROPANE; METHYLENE; COMPLEXES; BIS(TITANOCENYL)ACETYLENE COMPLEX;

D O I：

10.1002/cber.19921251007

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Bis(trimethylphosphane)titanocene (1) reacts with 2-methyl-1,1-diphenylcyclopropane (2) to give red crystalline (eta2-2-methylene-1,1-diphenylcyclopropane)(trimethylphosphane)titanocene (3). In solution complex 3 degrades smoothly to form the new Cp2Ti(PMe3) - C2 - Ti(PMe3)Cp2 complex 4, the crystal structure of which has been elucidated by an X-ray analysis.

引用

页码：2209 / 2212

页数：4

共 35 条

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