TRANSLATIONAL ENERGY-DEPENDENCE OF THE REACTIVE CROSS-SECTION OF THE C+NO-]CN+O REACTION STUDIED IN PULSED, CROSSED, SUPERSONIC MOLECULAR-BEAMS

被引：16

作者：

COSTES, M ^{[1
]}

NAULIN, C ^{[1
]}

GHANEM, N ^{[1
]}

DORTHE, G ^{[1
]}

机构：

[1] UNIV BORDEAUX 1,CNRS,GDR 87,F-33405 TALENCE,FRANCE

来源：

JOURNAL OF THE CHEMICAL SOCIETY-FARADAY TRANSACTIONS | 1993年 / 89卷 / 10期

关键词：

D O I：

10.1039/ft9938901501

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

The C(3P(J)) + NO(X 2PI(r)) --> CN(X 2SIGMA+) + O(3P(J)) reaction is studied using combined pulsed lasers and pulsed, crossed, supersonic molecular beams. The relative reactive cross-section is found to decrease slowly in the relative translational energy domain sampled, epsilon(tr) = 0.038 - 0.163 eV (1 eV almost-equal-to 1.602 18 x 10(19) J), with a dependence that can be fitted to a (epsilon(tr))-1/3 functionality.

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页码：1501 / 1504

页数：4

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