STABLE FLEXIBLE FIBERS AND RIGID TUBULES MADE FROM SINGLE-CHAIN PERFLUOROALKYLATED AMPHIPHILES

被引：62

作者：

GIULIERI, F ^{[1
]}

KRAFFT, MP ^{[1
]}

RIESS, JG ^{[1
]}

机构：

[1] UNIV NICE, FAC SCI, CNRS, UNITE CHIM MOLEC, F-06108 NICE 2, FRANCE

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 1994年 / 33卷 / 14期

关键词：

D O I：

10.1002/anie.199415141

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Up to 50 um long, stable, cylindrical aggregates (shown on the right) are formed spontaneously from dispersions of perfluoroalkylated, single‐chain, nonchiral amphiphiles derived from dimorpho‐linophosphoramidate and phosphocholine. Depending on the polar head group, rigid hollow tubules or thinner, longer, flexible fibers are obtained. Thus, the strong hydrophobic effect of the fluorinated chains alone appears to be sufficient to promote the formation of assemblies more stable than vesicles. (Figure Presented.) Copyright © 1994 by VCH Verlagsgesellschaft mbH, Germany

引用

页码：1514 / 1515

页数：2

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