STEREOCHEMISTRY OF FREE-RADICAL ADDITIONS OF METHANOL AND ACETALDEHYDE TO PERFLUORINATED CYCLOALKENES

被引：7

作者：

CHAMBERS, RD ^{[1
]}

KELLY, N ^{[1
]}

EMSLEY, JW ^{[1
]}

JONES, WGM ^{[1
]}

机构：

[1] ICI LTD,DIV PHARMACEUT,MACCLESFIELD SK10 4TG,CHESHIRE,ENGLAND

来源：

JOURNAL OF FLUORINE CHEMISTRY | 1979年 / 13卷 / 01期

关键词：

D O I：

10.1016/S0022-1139(00)85167-2

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

γ-Ray and peroxide-initiated additions of methanol and acetaldehyde to perfluorocyclo-butene (3), -pentene (4), and -hexene (5) gave mixtures of stereo-isomers in most cases. Stereospecific cis-addition of acetaldehyde to (5) occurs under γ-initiation. A simple 19F n.m.r. method is advanced to distinguish the geometric isomers. © 1978.

引用

页码：49 / 62

页数：14

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