CORRECTION PROCEDURES FOR RARE-EARTH ELEMENT ANALYSES IN INDUCTIVELY COUPLED PLASMA-MASS SPECTROMETRY

被引：63

作者：

VAUGHAN, MA ^{[1
]}

HORLICK, G ^{[1
]}

机构：

[1] UNIV ALBERTA,DEPT CHEM,EDMONTON T6G 2G2,ALBERTA,CANADA

来源：

APPLIED SPECTROSCOPY | 1990年 / 44卷 / 04期

关键词：

D O I：

10.1366/0003702904087488

中图分类号：

TH7 [仪器、仪表];

学科分类号：

0804 ; 080401 ; 081102 ;

摘要：

The analysis of the rare earth elements by inductively coupled plasma-mass spectrometry is complicated by spectral overlap problems involving M+, MO+, and MOH+ ions. Two correction schemes are compared in this study. One correction scheme is the classical algebraic approach (Gauss elimination) and the other is a method based on principal components analysis, also known as factor analysis. Both schemes work well, but the principal components analysis approach is considerably more flexible, is easier to expand to more elements, and can tolerate missing data.

引用

页码：587 / 593

页数：7

共 17 条

[1] CORRECTION OF INTERFERENCE EFFECTS IN THE DETERMINATION OF THE RARE-EARTH ELEMENTS AND HAFNIUM BY SPARK-SOURCE MASS-SPECTROMETRY [J].

BACON, JR ;

URE, AM .

ANALYTICA CHIMICA ACTA, 1979, 105 (01) :163-176

[2] MULTIVARIATE CALIBRATION OF INFRARED-SPECTRA FOR QUANTITATIVE-ANALYSIS USING DESIGNED EXPERIMENTS [J].

CAHN, F ;

COMPTON, S .

APPLIED SPECTROSCOPY, 1988, 42 (05) :865-872

[3] DETERMINATION OF RARE-EARTH ELEMENTS IN GEOLOGICAL SAMPLES BY INDUCTIVELY COUPLED PLASMA SOURCE-MASS SPECTROMETRY [J].

DATE, AR ;

HUTCHISON, D .

JOURNAL OF ANALYTICAL ATOMIC SPECTROMETRY, 1987, 2 (03) :269-276

[4] APPLICATION OF PRINCIPAL COMPONENT ANALYSIS ON NIR SPECTRAL COLLECTION AFTER ELIMINATION OF INTERFERENCE BY A LEAST-SQUARES PROCEDURE [J].

DEVAUX, MF ;

BERTRAND, D ;

ROBERT, P ;

QANNARI, M .

APPLIED SPECTROSCOPY, 1988, 42 (06) :1020-1023

[5] PARTIAL LEAST-SQUARES QUANTITATIVE-ANALYSIS OF INFRARED SPECTROSCOPIC DATA .2. APPLICATION TO DETERGENT ANALYSIS [J].

FULLER, MP ;

RITTER, GL ;

DRAPER, CS .

APPLIED SPECTROSCOPY, 1988, 42 (02) :228-235

[6] PARTIAL LEAST-SQUARES REGRESSION - A TUTORIAL [J].

GELADI, P ;

KOWALSKI, BR .

ANALYTICA CHIMICA ACTA, 1986, 185 :1-17

[7] PRECISE DETERMINATION OF RARE-EARTH ELEMENTS IN GEOLOGICAL STANDARD ROCKS BY INDUCTIVELY COUPLED PLASMA SOURCE-MASS SPECTROMETRY [J].

HIRATA, T ;

SHIMIZU, H ;

AKAGI, T ;

SAWATARI, H ;

MASUDA, A .

ANALYTICAL SCIENCES, 1988, 4 (06) :637-643

[8] DETERMINATION OF THE RARE-EARTH ELEMENTS IN GEOLOGICAL-MATERIALS BY INDUCTIVELY COUPLED PLASMA MASS-SPECTROMETRY [J].

LICHTE, FE ;

MEIER, AL ;

CROCK, JG .

ANALYTICAL CHEMISTRY, 1987, 59 (08) :1150-1157

[9]

LONGERICH HP, 1987, SPECTROCHIM ACTA, V42, P79

[10]

Malinowski E. R., 1980, FACTOR ANAL CHEM, V3

← 1 2 →