THE SOLUBILITY OF THE ALKALI AURIDES CSAU, RBAU AND KAU IN THE CORRESPONDING MOLTEN BROMIDES

被引：9

作者：

WORMUTH, R

SCHMUTZLER, RW

机构：

[1] Physikalische Chemie la, Universität Dortmund, 4600 Dortmund 50, Postfach 500 500, D

来源：

THERMOCHIMICA ACTA | 1990年 / 160卷 / 01期

关键词：

D O I：

10.1016/0040-6031(90)80249-X

中图分类号：

O414.1 [热力学];

学科分类号：

摘要：

The solubility of the alkali aurides MAu (M = K, Rb and Cs) in the corresponding alkali bromides has been determined by difference thermal analysis along the MAu/MBr section of the ternary M/Au/MBr phase diagrams. In the Cs system complete miscibility in the liquid and in the solid state is obtained whereas for the Rb system complete miscibility is only observed in the liquid state. In the K system, which changes from ionic to almost metallic charge transport with increasing KAu content, a miscibility gap appears even in the liquid state. © 1990.

引用

页码：97 / 102

页数：6

共 15 条

[1]

Bredig M.A., 1964, MOLTEN SALT CHEM, P367

[2]

Cox P. A, 1987, ELECT STRUCTURE CHEM, P45

[3]

DANSLAX D, 1970, TASCHENBUCH CHEM PHY, V3, P427

[4] A HIGH-TEMPERATURE DTA APPARATUS FOR LARGE AND HIGHLY CORROSIVE SAMPLES WITH HIGH VAPOR-PRESSURES [J].

GROB, W ;

SCHMUTZLER, RW .

THERMOCHIMICA ACTA, 1990, 160 (01) :33-38

[5]

HANEBECK D, 1986, THESIS DORTMUND

[6]

HOLZHEY C, 1985, J PHYS, P373

[7]

JACOBS H, 1987, COMMUNICATION

[8]

KIENAST VG, 1961, Z ANORG ALLG CHEM, V310, P143

[9] ELECTRONIC-PROPERTIES OF ALKALI-METAL GOLD COMPOUNDS [J].

KOENIG, C ;

CHRISTENSEN, NE ;

KOLLAR, J .

PHYSICAL REVIEW B, 1984, 29 (12) :6481-6488

[10]

KRUGER KD, 1976, BER BUNSEN PHYS CHEM, V80, P816, DOI 10.1002/bbpc.19760800835

← 1 2 →