INTERMEDIATES FROM LOW-TEMPERATURE PHOTOLYSIS OF 4,4'-DIAZIDOBIPHENYL IN RIGID MATRICES

被引：23

作者：

OHANA, T ^{[1
]}

KAISE, M ^{[1
]}

YABE, A ^{[1
]}

机构：

[1] NATL CHEM LAB IND, HIGASHI KU, TSUKUBA, IBARAKI 305, JAPAN

来源：

CHEMISTRY LETTERS | 1992年 / 08期

关键词：

D O I：

10.1246/cl.1992.1397

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The photolysis of 4,4'-diazidobiphenyl (1) in an Ar matrix at low-temperatures (15-20 K). was investigated by UV-vis and IR spectroscopies. The dinitrene was identified as an intermediate by using N-15-labeled 1 and by trapping of the nitrene with CO. The presence of didehydroazepine and quinonoid structures was excluded.

引用

页码：1397 / 1400

页数：4

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