SEGREGATION ON THE SURFACE OF STEELS IN HEAT-TREATMENT AND OXIDATION

被引:107
作者
GRABKE, HJ [1 ]
LEROY, V [1 ]
VIEFHAUS, H [1 ]
机构
[1] CTR RECH MET,LIEGE,BELGIUM
关键词
STEEL SURFACE; EQUILIBRIUM SEGREGATION; COSEGREGATION; CHEMISORPTION INDUCED SEGREGATION; MONOLAYER SURFACE COMPOUNDS; SURFACE PRECIPITATES; SELECTIVE OXIDATION; SEGREGATION BENEATH OXIDE SCALES;
D O I
10.2355/isijinternational.35.95
中图分类号
TF [冶金工业];
学科分类号
0806 ;
摘要
During annealing of steels different kinds of enrichments are observed on. steel surfaces. Equilibrium segregation of a dissolved element leads to enrichment in the range of a monolayer, two interacting elements can form two-dimensional compounds by cosegregation and also chemisorption induced segregation leads to monolayer surface compounds. If the concentrations or pressures are exceeded which are necessary for the formation of three-dimensional bulk compounds, enrichments occur due to surface precipitation resp. oxidation. On the other hand, oxidation can cause segregation or accumulations of dissolved elements beneath the oxide scale. These different phenomena are fundamentally discussed and examples are presented, which are important in the steel production and for the steel properties.
引用
收藏
页码:95 / 113
页数:19
相关论文
共 111 条
[1]  
ANDERSSON T, 1977, MET TECHNOL, P106
[2]  
ASAMI K, 1979, CORROS SCI, V19, P1007, DOI 10.1016/S0010-938X(79)80120-1
[3]  
BENMOSTEFA L, 1990, MATER SCI TECH SER, V6, P885, DOI 10.1179/026708390790193592
[4]  
BLAKELY JM, 1978, CRC CRIT R SOLID ST, P333
[5]  
COX AR, 1965, J IRON STEEL I, V203, P175
[6]  
DAVIS LE, 1976, HDB AUGER ELECTRON S
[7]  
DERUGY H, 1986, SURF SCI, V173, P418, DOI 10.1016/0039-6028(86)90200-1
[8]   INFLUENCE OF CHEMICAL INTERACTIONS BETWEEN METALLIC AND METALLOID SOLUTES ON THEIR SEGREGATION IN ALPHA-FE .1. CO-SEGREGATION AT FREE SURFACES STUDIED BY AUGER-ELECTRON SPECTROSCOPY [J].
DUMOULIN, P ;
GUTTMANN, M .
MATERIALS SCIENCE AND ENGINEERING, 1980, 42 (1-2) :249-263
[9]   EQUILIBRIUM SEGREGATION OF PHOSPHORUS AT GRAIN-BOUNDARIES OF FE-P, FE-C-P, FE-CR-P, AND FE-CR-C-P ALLOYS [J].
ERHART, H ;
GRABKE, HJ .
METAL SCIENCE, 1981, 15 (09) :401-408
[10]   SULFUR SEGREGATION DURING THE HIGH-TEMPERATURE OXIDATION OF CHROMIUM [J].
FOX, P ;
LEES, DG ;
LORIMER, GW .
OXIDATION OF METALS, 1991, 36 (5-6) :491-503