ROTATIONAL DIFFUSION DYNAMICS OF PERYLENE IN N-ALKANES - OBSERVATION OF A SOLVENT LENGTH-DEPENDENT CHANGE OF BOUNDARY-CONDITION

被引：94

作者：

JIANG, Y ^{[1
]}

BLANCHARD, GJ ^{[1
]}

机构：

[1] MICHIGAN STATE UNIV,DEPT CHEM,E LANSING,MI 48824

来源：

JOURNAL OF PHYSICAL CHEMISTRY | 1994年 / 98卷 / 26期

关键词：

D O I：

10.1021/j100077a003

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

We report on the orientational relaxation dynamics of perylene in both its ground electronic state and its first excited singlet electronic state in the series of n-alkanes n-pentane through n-decane, n-dodecane, and n-hexadecane. We observe a curvilinear relationship between orientational relaxation time and solvent viscosity and interpret these data in terms of a solvent length-dependent change in the nature of solvent-solute interactions.

引用

页码：6436 / 6440

页数：5

共 44 条

[1] THE INFLUENCE OF WAVE VECTOR DEPENDENT DIELECTRIC-PROPERTIES ON ROTATIONAL FRICTION - ROTATIONAL DIFFUSION OF PHENOXAZINE DYES
ALAVI, DS
HARTMAN, RS
WALDECK, DH
[J]. JOURNAL OF CHEMICAL PHYSICS, 1991, 95 (09) : 6770 - 6783
[2] SHOT-NOISE-LIMITED DETECTION SCHEME FOR 2-BEAM LASER SPECTROSCOPIES
ANDOR, L
LORINCZ, A
SIEMION, J
SMITH, DD
RICE, SA
[J]. REVIEW OF SCIENTIFIC INSTRUMENTS, 1984, 55 (01) : 64 - 67
[3] MULTIPLE MODULATION FOR OPTICAL PUMP-PROBE SPECTROSCOPY
BADO, P
WILSON, SB
WILSON, KR
[J]. REVIEW OF SCIENTIFIC INSTRUMENTS, 1982, 53 (05) : 706 - 707
[4] DYNAMICS OF FLUORESCENCE POLARIZATION IN MACROMOLECULES
BELFORD, GG
BELFORD, RL
WEBER, G
[J]. PROCEEDINGS OF THE NATIONAL ACADEMY OF SCIENCES OF THE UNITED STATES OF AMERICA, 1972, 69 (06) : 1392 - &
[5] THE SOLUTE SIZE EFFECT IN ROTATIONAL DIFFUSION EXPERIMENTS - A TEST OF MICROSCOPIC FRICTION THEORIES
BENAMOTZ, D
DRAKE, JM
[J]. JOURNAL OF CHEMICAL PHYSICS, 1988, 89 (02) : 1019 - 1029
[6] MICROSCOPIC FRICTIONAL FORCES ON MOLECULAR-MOTION IN LIQUIDS - PICOSECOND ROTATIONAL DIFFUSION IN ALKANES AND ALCOHOLS
BENAMOTZ, D
SCOTT, TW
[J]. JOURNAL OF CHEMICAL PHYSICS, 1987, 87 (07) : 3739 - 3748
[7] STATE-DEPENDENT REORIENTATION CHARACTERISTICS OF METHYLENE-BLUE - THE IMPORTANCE OF DIPOLAR SOLVENT SOLUTE INTERACTIONS
BLANCHARD, GJ
[J]. JOURNAL OF PHYSICAL CHEMISTRY, 1989, 93 (10) : 4315 - 4319
[8] ANOMALOUS TEMPERATURE-DEPENDENT REORIENTATION OF CRESYL VIOLET IN 1-DODECANOL
BLANCHARD, GJ
WIRTH, MJ
[J]. JOURNAL OF PHYSICAL CHEMISTRY, 1986, 90 (11) : 2521 - 2525
[9] DETECTION OF A TRANSIENT SOLVENT SOLUTE COMPLEX USING TIME-RESOLVED PUMP PROBE SPECTROSCOPY
BLANCHARD, GJ
[J]. ANALYTICAL CHEMISTRY, 1989, 61 (21) : 2394 - 2398
[10] ORIENTATIONAL RELAXATION DYNAMICS OF OXAZINE-118 AND RESORUFIN IN THE BUTANOLS - VALENCE-DEPENDENT AND STATE-DEPENDENT SOLVATION EFFECTS
BLANCHARD, GJ
CIHAL, CA
[J]. JOURNAL OF PHYSICAL CHEMISTRY, 1988, 92 (21) : 5950 - 5954

← 1 2 3 4 5 →