OXIDATIONS OF AMINES .9. CORRELATION OF RATE CONSTANTS FOR REVERSIBLE ONE-ELECTRON TRANSFER IN AMINE OXIDATION WITH REACTANT POTENTIALS

被引：45

作者：

HULL, LA

DAVIS, GT

ROSENBLA.DH

机构：

[1] Research Laboratories, Edgewood Arsenal, Edgewood Arsenal

来源：

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY | 1969年 / 91卷 / 23期

关键词：

D O I：

10.1021/ja01051a009

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A correlation between the logarithms of the rate constants for triethylamine oxidation by several oxidants and the oxidation potentials of the oxidants has been found. These oxidants include chlorine dioxide, permanganate, ferric, molybdicyanide, ferricyanide, and several ferric phenanthroline complexes. Also correlations for predicting the rates of amine oxidations from the oxidation potentials of the oxidants and the photoionization potentials or Σσ* of the amines have been developed. Strong retardation by ferrocyanide in the oxidation of triethylamine by ferricyanide has been observed. © 1969, American Chemical Society. All rights reserved.

引用

页码：6247 / &

共 42 条

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