ELECTRO-ORGANIC REACTIONS .13. ANODIC-ACETOXYLATION OF METHYL OLEATE

被引：5

作者：

ADAMS, C ^{[1
]}

FRANKEL, EN ^{[1
]}

UTLEY, JHP ^{[1
]}

机构：

[1] UNIV LONDON, QUEEN MARY COLL, DEPT CHEM, LONDON E1 4NS, ENGLAND

来源：

JOURNAL OF THE CHEMICAL SOCIETY-PERKIN TRANSACTIONS 1 | 1979年 / 02期

关键词：

D O I：

10.1039/p19790000353

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Efficient anodic mono- and di-acetoxylation of methyl oleate is described. Acetoxylation is consecutive and conditions may be adjusted to give a maximum of either 60% monoacetoxylation or 85% diacetoxylation. Both mono- and di-substituted products are a complex mixture of isomers but the products of exhaustive electrolysis are mainly 9,10-diacetoxyoctadec-7- or -11-enoate. A mechanistic rationalisation is proposed.

引用

页码：353 / 356

页数：4

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