STEREOSELECTIVE ALDOL REACTIONS OF GAMMA-THIOBUTYROLACTONE - THE BENZALDEHYDE ANOMALY

被引：4

作者：

GENNARI, C

OLIVA, A

MOLINARI, F

PIARULLI, U

机构：

[1] Dipartimento di Chimica Organica e Industriale, Università di Milano, Centro CNR Sost. Org. Nat., 20133 Milano

来源：

TETRAHEDRON LETTERS | 1990年 / 31卷 / 17期

关键词：

D O I：

10.1016/S0040-4039(00)97387-8

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Different protocols (lithium enolate reactions, fluoride catalyzed and Lewis acid mediated silyl ketene acetal reactions) were studied to achieve stereoselectivity in the aldol reactions of γ-thiobutyrolactone: in all cases benzaldehyde showed a striking peculiarity compared to aliphatic aldehydes. © 1990.

引用

页码：2453 / 2456

页数：4

共 17 条

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