KINETICS OF CONTRACTION OF DRAWN NYLON 66 IN AQUEOUS PHENOL

被引：3

作者：

JACOBS, MI

REBENFEL.L

TAYLOR, HS

机构：

[1] Textile Research Institute, Department of Chemistry, Princeton University, Princeton, New Jersey

来源：

JOURNAL OF APPLIED POLYMER SCIENCE | 1969年 / 13卷 / 03期

关键词：

D O I：

10.1002/app.1969.070130303

中图分类号：

O63 [高分子化学（高聚物）];

学科分类号：

070305 ; 080501 ; 081704 ;

摘要：

The rate of contraction of drawn nylon 66 in aqueous phenol was investigated, and a method is described for correlating this contraction with a series of elementary rate processes. The rate constants so obtained were analyzed by absolute rate theory, and the variations of ΔH† and ΔS† with phenol concentration gave evidence of the nature of the reaction steps. Copyright © 1969 John Wiley & Sons, Inc.

引用

页码：427 / &

共 9 条

[1] Brandt W. W., 1963, J APPL POLYM SCI, V7, P1919
[2] Cannon C.G, 1955, MIKROCHIM ACTA, V2-3, P555
[3] CHAIN FOLDING IN ORIENTED 66-NYLON FIBERS
DISMORE, PF
STATTON, WO
[J]. JOURNAL OF POLYMER SCIENCE PART B-POLYMER LETTERS, 1964, 2 (12P): : 1113 - &
[4] FORWARD MV, 1954, J TEXT I, V45, pT510
[5] FORWARD MV, 1950, J TEXT I, V41, pT267
[6] Glasstone S, 1941, THEORY RATE PROCESSE
[7] LAIDLER KJ, 1965, CHEMICAL KINETICS
[8] RATH H, 1957, TEXTIL PRAXIS, V12, P904
[9] PROPERTIES AND STRUCTURE OF NYLON FIBERS IN RELATION TO DRAWING AND AQUEOUS PHENOL TREATMENTS
SAKUMA, Y
REBENFEL.L
[J]. JOURNAL OF APPLIED POLYMER SCIENCE, 1966, 10 (04) : 637 - &

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