SYNTHESIS OF NEW ACENAPHTHYLENE FUNCTIONAL-DERIVATIVES .1. 1-(TRIMETHYLSILYL)-ACENAPHTHYLENES AND 1,2-ACENAPHTHYLENES AND 1,5-BIS(TRIMETHYLSILYL)ACENAPHTHYLENES AND RELATED COMPOUNDS

被引：18

作者：

LAGUERRE, M

FELIX, G

DUNOGUES, J

CALAS, R

机构：

[1] CNRS,CHIM ORGAN LAB,F-33405 TALENCE,FRANCE

[2] CNRS,CHIM COMPOSES ORGAN SILICIUM & ETAIN LAB,F-33405 TALENCE,FRANCE

来源：

JOURNAL OF ORGANIC CHEMISTRY | 1979年 / 44卷 / 24期

关键词：

D O I：

10.1021/jo01338a012

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

The title compounds were prepared from acenaphthylene la or acenaphthene 2a by appropriate silylation reactions followed by oxidation. Of the various reagents used for oxidation, n-BuLi-TMEDA-CdCl2 (Harvey's reagent) was found to be the most convenient, as it did not induce partial desilylation. The photoisomerization of 1,3-bis(l-acenaphthylenyl)tetramethyldisiloxane lg was also studied. © 1979, American Chemical Society. All rights reserved.

引用

页码：4275 / 4278

页数：4

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