SYNTHESIS BASED ON CYCLOHEXADIENES .9. TOTAL SYNTHESIS OF (PLUS-OR-MINUS)-SEYCHELLENE

被引：10

作者：

RAO, GSRS

BHASKAR, KV

机构：

来源：

JOURNAL OF THE CHEMICAL SOCIETY-PERKIN TRANSACTIONS 1 | 1993年 / 22期

关键词：

D O I：

10.1039/p19930002813

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

A new strategy for the total synthesis of (+/-)-seychellene 1 is described. The key step is an intramolecular Michael addition involving a 6-exo cyclisation with a vinyl radical derived from the acetylenic compound 11, obtained from the bicyclo[2.2.2]octene adduct 5 to the tricyclic intermediates 14 and 15.

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页码：2813 / 2816

页数：4

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