SYNTHESIS BASED ON CYCLOHEXADIENES .9. TOTAL SYNTHESIS OF (PLUS-OR-MINUS)-SEYCHELLENE

被引:10
作者
RAO, GSRS
BHASKAR, KV
机构
来源
JOURNAL OF THE CHEMICAL SOCIETY-PERKIN TRANSACTIONS 1 | 1993年 / 22期
关键词
D O I
10.1039/p19930002813
中图分类号
O62 [有机化学];
学科分类号
070303 ; 081704 ;
摘要
A new strategy for the total synthesis of (+/-)-seychellene 1 is described. The key step is an intramolecular Michael addition involving a 6-exo cyclisation with a vinyl radical derived from the acetylenic compound 11, obtained from the bicyclo[2.2.2]octene adduct 5 to the tricyclic intermediates 14 and 15.
引用
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页码:2813 / 2816
页数:4
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