METAL-COMPLEXES OF MARINE PEPTIDE METABOLITES - A NOVEL AG-4 CLUSTER

被引：54

作者：

WIPF, P

VENKATRAMAN, S

MILLER, CP

GEIB, SJ

机构：

[1] Department of Chemistry, University of Pittsburgh, Pittsburgh, Pennsylvania

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 1994年 / 33卷 / 14期

关键词：

D O I：

10.1002/anie.199415161

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Silver(I) ions are bound selectively and with high cooperativity to the peptide westiellamide obtained from Lisso‐clinum. The complex contains a unique [Ag4]4+ cluster sandwiched between two neutral macrocyclic ligands (see structure on the right). The importance of metal chelation for the biological activity is currently under investigation. (Figure Presented.) Copyright © 1994 by VCH Verlagsgesellschaft mbH, Germany

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页码：1516 / 1518

页数：3

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