SYNTHESIS AND STRUCTURE OF THE MAGNESIUM IMIDE [(THF)MGNPH](6)

被引:61
作者
HASCALL, T [1 ]
RUHLANDTSENGE, K [1 ]
POWER, PP [1 ]
机构
[1] UNIV CALIF DAVIS,DEPT CHEM,DAVIS,CA 95616
来源
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH | 1994年 / 33卷 / 03期
关键词
D O I
10.1002/anie.199403561
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
A hexagonal prism, in which the two parallel six‐membered rings of alternating Mg and N atoms are almost planar, forms the molecular framework of the title compound (Ph and THF substituents are represented by ipso‐C and O atoms, respectively, in the picture shown on the right). This compound, which can be readily synthesized from Et2Mg and H2NPh in ether, is the first well‐characterized magnesium imide. (Figure Presented.) Copyright © 1994 by VCH Verlagsgesellschaft mbH, Germany
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页码:356 / 357
页数:2
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