EFFECT OF ABSORBED WATER ON DYNAMIC MECHANICAL PROPERTIES OF SOME POLYAMIDES

被引:29
作者
JACKSON, JB
机构
[1] I.C.I. Ltd, Petrochemical and Polymer Laboratory, Runcorn, Cheshire, P.O. Box 11, The Heath
关键词
D O I
10.1016/0032-3861(69)90026-3
中图分类号
O63 [高分子化学(高聚物)];
学科分类号
070305 ; 080501 ; 081704 ;
摘要
The dynamic mechanical properties of poly(hexamethylene isophthalamide) and poly(dodecamethylene terephthalamide) have been determined over a wide range of temperature at low frequencies (∼ 1 c/s) by torsion pendulum measurements and at high frequencies (∼ 500 c/s) by a vibrating reed technique. It has been shown that absorbed moisture leads to the appearance of an intermediate loss peak at temperatures in the range -20°C to -70°C, between the main glass/rubber transition at 120°C and a low temperature process with a peak near -150°C. Unlike other polyamides such as nylon 6-6, the main glass/rubber transition is unaffected by moisture. © 1969.
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页码:159 / &
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