ELECTROORGANIC CHEMISTRY .130. A NOVEL TRIFLUOROMETHYLATION OF ALDEHYDES AND KETONES PROMOTED BY AN ELECTROGENERATED BASE

被引：114

作者：

SHONO, T

ISHIFUNE, M

OKADA, T

KASHIMURA, S

机构：

[1] Department of Synthetic Chemistry, Faculty of Engineering, Kyoto University, Yoshida, Sakyo

来源：

JOURNAL OF ORGANIC CHEMISTRY | 1991年 / 56卷 / 01期

关键词：

D O I：

10.1021/jo00001a002

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

A base generated by the electroreduction of 2-pyrrolidone deprotonated trifluoromethane to form a trifluoromethyl anion equivalent. In the presence of hexamethyldisilazane, this species reacted with a variety of aldehydes and ketones to afford (trifluoromethyl)-carbinols in high yield.

引用

页码：2 / 4

页数：3

共 17 条

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