SYNTHESIS AND CHARACTERIZATION OF 1,3-DISUBSTITUTED DECAMETHYLCYCLOHEXASILANES

被引：22

作者：

HENGGE, E

EIBL, M

机构：

[1] Institut für Anorganische Chemie der TU-Graz, A-8010 Graz

来源：

JOURNAL OF ORGANOMETALLIC CHEMISTRY | 1992年 / 428卷 / 03期

关键词：

D O I：

10.1016/0022-328X(92)83096-Z

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The reaction of SbCl5 with Si6Me12 yields 1,3- and 1,4-Cl2Si6Me10. In order to isolate these isomers, a mixture of 1,3- and 1,4-[Fe(CO)2Cp]2Si6Me10 was synthesized and separated by fractional extraction with benzene. The structure of 1,3-[Fe(CO)2Cp]2Si6Me10 has been revealed by Si-29-INEPT-INADEQUATE spectroscopy. Starting from 1,3-[Fe(CO)2Cp]2Si6Me10, the compounds 1,3-Cl2Si6Me10, 1,3-Br2Si6Me10 and 1,3-H2Si6Me10 were synthesized and characterized.

引用

页码：335 / 343

页数：9

共 5 条

[1]

DETTY MR, 1982, J ORG CHEM, V47, P1454

[2] NEW CYCLOHEXASILANYL DERIVATIVES WITH COBALT AND IRON SUBSTITUENTS [J].