IODINE AZIDE

被引：44

作者：

BUZEK, P

KLAPOTKE, TM

SCHLEYER, PV

TORNIEPORTHOETTING, IC

WHITE, PS

机构：

[1] TECH UNIV BERLIN,INST ANORGAN & ANALYT CHEM,STR 17 JUNI 135,W-1000 BERLIN 12,GERMANY

[2] UNIV ERLANGEN NURNBERG,INST ORGAN CHEM,W-8520 ERLANGEN,GERMANY

[3] UNIV N CAROLINA,DEPT CHEM,CHAPEL HILL,NC 27599

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH | 1993年 / 32卷 / 02期

关键词：

D O I：

10.1002/anie.199302751

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Very pure and crystalline, iodine azide IN3 (1) can be obtained by reaction of silver azide and iodine in CFCl3 and subsequent sublimation. According to the results of the X-ray structure analysis in the solid state IN3 consists of layers of chains, which contain twofold coordinated iodine atoms. The structural parameters of the IN3 unit are in good agreement with the results of an ab initio calculation for IN3.

引用

页码：275 / 277

页数：3

共 23 条

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