PREPARATION OF POLY(3,4-DIBUTOXY-2,5-THIENYLENE-VINYLENE) VIA TITANIUM-INDUCED DICARBONYL-COUPLING REACTION OF 3,4-DIBUTOXYTHIOPHENE-2,5-DICARBALDEHYDE

被引：18

作者：

IWATSUKI, S

KUBO, M

ITOH, Y

机构：

来源：

CHEMISTRY LETTERS | 1993年 / 07期

关键词：

D O I：

10.1246/cl.1993.1085

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

3,4-Dibutoxythiophene-2,5-dicarbaldehyde was found to be readily subject to the titanium-induced dicarbonyl-coupling reaction to give poly(3,4-dibutoxy-2,5-thienylene-vinylene) with molecular weight of 35000 and high solubility in organic solvent like chloroform. In addition electroconductivity and third-order nonlinear optical susceptibility for its polymer film were measured.

引用

页码：1085 / 1088

页数：4

共 12 条

[1] BLOHM M, 1992, CHEM TECH, P105
[2] AN INVESTIGATION OF POLYMERIZATION VIA REDUCTIVE COUPLING OF CARBONYLS
COOKE, AW
WAGENER, KB
[J]. MACROMOLECULES, 1991, 24 (06) : 1404 - 1407
[3] FERINGA BL, 1988, SYNTHESIS-STUTTGART, P316
[4] HIGHLY-CONDUCTING, POLY(2,5-THIENYLENE VINYLENE) PREPARED VIA A SOLUBLE PRECURSOR POLYMER
JEN, KY
MAXFIELD, M
SHACKLETTE, LW
ELSENBAUMER, RL
[J]. JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1987, (04) : 309 - 311
[5] HIGHLY CONDUCTING, SOLUBLE, AND ENVIRONMENTALLY-STABLE POLY(3-ALKYLTHIOPHENES)
JEN, KY
MILLER, GG
ELSENBAUMER, RL
[J]. JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1986, (17) : 1346 - 1347
[6] KOSSMEHL G, 1970, MAKROMOL CHEM, V131, P15
[7] TITANIUM-INDUCED DICARBONYL-COUPLING REACTIONS
MCMURRY, JE
[J]. ACCOUNTS OF CHEMICAL RESEARCH, 1983, 16 (11) : 405 - 411
[8] MURASE I, 1987, POLYM COMMUN, V28, P229
[9] SOLUBLE CONDUCTING POLYTHIOPHENES
SATO, M
TANAKA, S
KAERIYAMA, K
[J]. JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1986, (11) : 873 - 874
[10] Steinkopf W, 1934, LIEBIGS ANN CHEM, V512, P136

← 1 2 →