(TRIS[N-(SALICYLIDENE)-2-AMINOETHYL]AMINE)COBALT(III) ACETONITRILE HEMIHYDRATE

被引：20

作者：

ELERMAN, Y ^{[1
]}

KABAK, M ^{[1
]}

SVOBODA, I ^{[1
]}

GESELLE, M ^{[1
]}

机构：

[1] TH DARMSTADT,FACHBEREICH MAT WISSENSCH,D-64287 DARMSTADT,GERMANY

来源：

ACTA CRYSTALLOGRAPHICA SECTION C-CRYSTAL STRUCTURE COMMUNICATIONS | 1994年 / 50卷

关键词：

D O I：

10.1107/S0108270194005871

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The slightly distorted octahedral coordination sphere of cobalt in {2,2',2''-[nitrilotris(ethylenenitrilomethylidyne-kappa N)]triphenolato-kappa(3) O}cobalt(III) acetonitrile hemihydrate, [Co(C27H27N4O3)].CH3CN.0.5H2O, is formed from three N and three O atoms which are in a fac arrangement. The chelate rings formed by the salicylidene-imine moieties are almost planar [maximum deviation of the Co atom from a least-squares plane calculated for the atoms of a salicylidene-imine moiety is 0.101 (4) Angstrom]. Average bond lengths are 1.893 (3) Angstrom for Co-O and 1.947 (4) Angstrom for Co-N.

引用

页码：1694 / 1696

页数：3

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