On the quadrupole splitting in ferrous compounds

被引:21
作者
Ganiel, U. [1 ]
机构
[1] Carnegie Mellon Univ, Dept Phys, Pittsburgh, PA 15213 USA
关键词
D O I
10.1016/0009-2614(69)85076-1
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
It is shown that the major contribution to the low temperature "saturation" value of the quadrupole splitting in ferrous compounds is independent (with a few well-defined exceptions) on the site symmetry of the Fe2+ ion. This explains the experimental fact that the measured values of this quantity in most compounds fall within approximate to 20% of each other.
引用
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页码:87 / 88
页数:2
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