THE PREPARATION AND ALLYLATION OF PERFLUOROALLYL CADMIUM AND COPPER REAGENTS

被引：20

作者：

BURTON, DJ

TARUMI, Y

HEINZE, PL

机构：

[1] Department of Chemistry, University of Iowa, Iowa City

来源：

JOURNAL OF FLUORINE CHEMISTRY | 1990年 / 50卷 / 02期

基金：

美国国家科学基金会;

关键词：

D O I：

10.1016/S0022-1139(00)80501-1

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Perfluoroallyl iodide reacts readily with acid-washed cadmium powder in DMF at 0°C to give the F-allylcadmium reagent. Metathesis of F-allylcadmium with Cu(I)Br at -35° C in DMF gives the F-allylcopper reagent. With zinc powder, perfluoroallyl iodide affords mainly F-1,5-hexadiene. Only a low yield of F-allylzinc was detected. Both F-allylcadmium and F-allylcopper react with allyl bromide to yield 1,1,2,3,3-pentafluoro-1,5-hexadiene. © 1990.

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页码：257 / 263

页数：7

相关论文

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