PHEROMONE SYNTHESIS .29. STEREOCONTROLLED SYNTHESIS OF ALL OF THE 4 POSSIBLE STEREOISOMERS OF ERYTHRO-3,7-DIMETHYLPENTADEC-2-YL ACETATE AND PROPIONATE, THE SEX-PHEROMONE OF THE PINE SAWFLIES

被引：74

作者：

MORI, K

TAMADA, S

机构：

[1] Department of Agricultural Chemistry, The University of Tokyo, Bunkyo-ku, Tokyo, 113

来源：

TETRAHEDRON | 1979年 / 35卷 / 10期

关键词：

D O I：

10.1016/0040-4020(79)80054-X

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

All of the four possible stereoisomers of 2,3-erythro-3,7-dimethylpentadecan-2-ol 1 were synthesized by a stereospecific SN2 oxirane cleavage of (2S,3S)-2,3-epoxybutane or its antipode with lithium di[(R)- or (S)-4-methyldodecyl]cuprate. Their acetates or propionates were prepared to test their pheromone activity. © 1979.

引用

页码：1279 / 1284

页数：6

共 15 条

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