THE USE OF H-2 NMR IN THE ELUCIDATION OF THE CATALYTIC PATHWAY OF THE HYDROFORMYLATION REACTION

被引：25

作者：

UCCELLOBARRETTA, G

LAZZARONI, R

SETTAMBOLO, R

SALVADORI, P

机构：

[1] CNR,CTR STUDIO MACROMOLEC STEREORDINATE & OTTICAMENTE ATT,DIPARTIMENTO CHIM & CHIM IND,I-56126 PISA,ITALY

[2] IST CHIM QUANTIST & ENERGET MOLEC,I-56126 PISA,ITALY

来源：

JOURNAL OF ORGANOMETALLIC CHEMISTRY | 1991年 / 417卷 / 1-2期

关键词：

D O I：

10.1016/0022-328X(91)80165-G

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Differences in the behaviour of the metal-alkyl intermediates involved in the deuterioformylation of styrene in the presence of Co2(CO)8 or Rh4(CO)12 as catalytic precursors, have been readily revealed by H-2 NMR analysis of the crude mixtures present after partial conversion. The results clearly demonstrate the value of this simple method for mechanistic studies of catalytic reactions.

引用

页码：111 / 119

页数：9

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