INVESTIGATION OF THE ELECTROCHEMICAL REDUCTION OF [CP-ASTERISK-RE(CO)2(P-N2C6H4OME)][BF4] BY SCANNING ELECTROCHEMICAL MICROSCOPY

被引：12

作者：

RICHARDS, TC

BARD, AJ

CUSANELLI, A

SUTTON, D

机构：

[1] UNIV TEXAS, DEPT CHEM & BIOCHEM, AUSTIN, TX 78712 USA

[2] SIMON FRASER UNIV, DEPT CHEM, BURNABY V5A 1S6, BC, CANADA

来源：

ORGANOMETALLICS | 1994年 / 13卷 / 03期

关键词：

D O I：

10.1021/om00015a006

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The reduction of the rhenium aryldiazenido complex [Cp*Re(CO)2(p-N2C6H4OMe)] [BF4] results in the formation of the corresponding metal-bound dinitrogen complex Cp*Re(CO)2(N2). The mechanism of this transformation has been investigated by cyclic voltammetry (CV), controlled-potential electrolysis (CPE), and scanning electrochemical microscopy (SECM). The SECM analysis supported an electrochemical ErCi mechanism for the reduction of the cationic aryldiazenido complex to the neutral dinitrogen complex.

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页码：757 / 759

页数：3

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