RELATIVE REACTIVITIES OF SUBSTITUTED OLEFINS TOWARD BENZYNE

被引：25

作者：

TABUSHI, I

OKAZAKI, K

ODA, R

机构：

[1] Department of Synthetic Chemistry, Kyoto University, Sakyo-ku, Kyoto

来源：

TETRAHEDRON | 1969年 / 25卷 / 18期

关键词：

D O I：

10.1016/S0040-4020(01)82980-X

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

In the reaction of various substituted olefins with benzyne, product determination and relative reactivity measurements were carried out. The principal reaction is the addition-H migration. Orientation of the first addition (concerning with the substituent on the double bond) and acceleration with acetyl, methoxycarbonyl, aluoxyl or alkyl substituent revealed that a biradical intermediate is involved. © 1969.

引用

页码：4401 / &

共 21 条

[1]

BEKE D, 1963, CA5633, V58

[2] FORMATION + CAPTURE OF REACTIVE INTERMEDIATE RELATED TO DIMETHYLPSEUDOINDENE [J].