PHENYL TRANSFER FROM SILICON TO PLATINUM VIA THE ORTHO METALATION OF A PHENYLSILYL LIGAND

被引：40

作者：

CHANG, LS ^{[1
]}

JOHNSON, MP ^{[1
]}

FINK, MJ ^{[1
]}

机构：

[1] TULANE UNIV,DEPT CHEM,NEW ORLEANS,LA 70118

来源：

ORGANOMETALLICS | 1991年 / 10卷 / 05期

关键词：

D O I：

10.1021/om00051a001

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The first isolated complex resulting from the ortho metalation of an arylsilyl ligand is reported. Thermolysis of the polysilylplatinum complex 1 in benzene-MeOH gives the cyclometalated species 2. Complex 2 is readily cleaved by water on silica to give the novel platinum compound 3 with a Pt-Ph bond and a silanol moiety on the polysilyl ligand.

引用

页码：1219 / 1221

页数：3

共 21 条

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