TEMPERATURE-DEPENDENCE OF THE INFRARED-SPECTRA OF C-60 - ORIENTATIONAL TRANSITION AND FREEZING

被引：25

作者：

BABU, VS ^{[1
]}

SEEHRA, MS ^{[1
]}

机构：

[1] W VIRGINIA UNIV,DEPT PHYS,MORGANTOWN,WV 26506

来源：

CHEMICAL PHYSICS LETTERS | 1992年 / 196卷 / 06期

关键词：

D O I：

10.1016/0009-2614(92)85995-M

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

The temperature dependence (8-350 K) of the position and intensity of the IR modes of C60 near 526, 576, 1182 and 1430 cm-1 is reported. Data indicate a phase transition T0 near 260 K and support the model of a glassy state below almost-equal-to 100 K predicted recently by molecular dynamic calculations. The first-order nature of T0 is smeared by impurities in the sample.

引用

页码：569 / 572

页数：4

共 14 条

[1] LOW-TEMPERATURE SPECIFIC-HEAT OF C-60
BEYERMANN, WP
HUNDLEY, MF
THOMPSON, JD
DIEDERICH, FN
GRUNER, G
[J]. PHYSICAL REVIEW LETTERS, 1992, 68 (13) : 2046 - 2049
[2] MOLECULAR-DYNAMICS INVESTIGATION OF ORIENTATIONAL FREEZING IN SOLID C-60
CHENG, A
KLEIN, ML
[J]. PHYSICAL REVIEW B, 1992, 45 (04): : 1889 - 1895
[3] MOLECULAR VIBRATIONS OF FOOTBALLENE
CYVIN, SJ
BRENDSDAL, E
CYVIN, BN
BRUNVOLL, J
[J]. CHEMICAL PHYSICS LETTERS, 1988, 143 (04) : 377 - 380
[4] ORIENTATIONAL DISORDER AND ELECTRONIC STATES IN C-60 AND A3C60, WHERE A IS AN ALKALI-METAL
GELFAND, MP
LU, JP
[J]. PHYSICAL REVIEW LETTERS, 1992, 68 (07) : 1050 - 1053
[5] DISCONTINUOUS VOLUME CHANGE AT THE ORIENTATIONAL-ORDERING TRANSITION IN SOLID C-60
HEINEY, PA
VAUGHAN, GBM
FISCHER, JE
COUSTEL, N
COX, DE
COPLEY, JRD
NEUMANN, DA
KAMITAKAHARA, WA
CREEGAN, KM
COX, DM
MCCAULEY, JP
SMITH, AB
[J]. PHYSICAL REVIEW B, 1992, 45 (08): : 4544 - 4547
[6] HEINEY PA, 1991, PHYS REV LETT, V66, P249
[7] HIGH-PRESSURE INFRARED SPECTROSCOPIC STUDY OF BUCKMINSTERFULLERENE, C60
HUANG, YN
GILSON, DFR
BUTLER, IS
[J]. JOURNAL OF PHYSICAL CHEMISTRY, 1991, 95 (15) : 5723 - 5725
[8] THE INFRARED AND ULTRAVIOLET-ABSORPTION SPECTRA OF LABORATORY-PRODUCED CARBON DUST - EVIDENCE FOR THE PRESENCE OF THE C-60 MOLECULE
KRATSCHMER, W
FOSTIROPOULOS, K
HUFFMAN, DR
[J]. CHEMICAL PHYSICS LETTERS, 1990, 170 (2-3) : 167 - 170
[9] LU JP, 1992, PHYS REV LETT, V68, P1050
[10] STRUCTURES AND VIBRATIONAL FREQUENCIES OF C60, C70, AND C84
RAGHAVACHARI, K
ROHLFING, CM
[J]. JOURNAL OF PHYSICAL CHEMISTRY, 1991, 95 (15) : 5768 - 5773

← 1 2 →