AN UNUSUAL STRUCTURE OF THE HYDRATED SODIUM-CHLORIDE COMPLEX OF CRYPTAND-[2.2.2]

被引:11
作者
DALLEY, NK [1 ]
KRAKOWIAK, KE [1 ]
BRADSHAW, JS [1 ]
KOU, XL [1 ]
IZATT, RM [1 ]
机构
[1] IBC ADV TECHNOL INC,AMER FORK,UT 84003
关键词
D O I
10.1002/jhet.5570320418
中图分类号
O62 [有机化学];
学科分类号
070303 ; 081704 ;
摘要
The solid state structure of the Na[2.2.2]Cl . 3H(2)O complex has the sodium ion displaced towards one of the cryptand nitrogens and the chloride and water molecules associated by hydrogen bonds to form a pseudo cube with two chloride ions at opposite corners of the cube and water oxygens at the other six corners.
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页码:1201 / 1204
页数:4
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