SYNTHESIS AND REACTIONS OF ESTER-SUBSTITUTED FULVENES - A NEW ROUTE TO DELTA-9(12)-CAPNELLENE

被引：20

作者：

WANG, Y ^{[1
]}

MUKHERJEE, D ^{[1
]}

BIRNEY, D ^{[1
]}

HOUK, KN ^{[1
]}

机构：

[1] UNIV CALIF LOS ANGELES,DEPT CHEM & BIOCHEM,LOS ANGELES,CA 90024

来源：

JOURNAL OF ORGANIC CHEMISTRY | 1990年 / 55卷 / 15期

关键词：

D O I：

10.1021/jo00302a004

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

: The condensation of cyclopentadienecarboxylic acid ester with aldehydes produces ester-substituted fulvenes regioselectively. The products undergo both intermolecular and intramolecular [6 + 2] cycloadditions to give the synthetically useful linearly fused tricyclopentanoids. A formal synthesis of Δ9(12)-capnellene is reported. © 1990, American Chemical Society. All rights reserved.

引用

页码：4504 / 4506

页数：3

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